2-Diphenylphosphanyl-1-methyl-1H-benzimidazole

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2-Di­phenyl­phosphanyl-1-methyl-1H-benzimidazole

In the title compound, C20H18N2P, the P atom is bonded to the two phenyl and imidazole groups, with an average P-C bond length of 1.828 (2) Å. The three C-P-C bond angles have values consistent with a tetra-hedral geometry around the P atom with the fourth site occupied by a H atom. Crystal packing is through van der Waals inter-actions.

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1-Methyl-1H-benzimidazole-2(3H)-thione

The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzene H atom and the benzene ring of a neighbouring mol-ecule, and by inter-molecular N-H⋯S inter-actions.

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1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone

The title compound C(8)H(8)N(2)Se, is the product of the reaction of 2-chloro-1-methyl-benzimidazole with sodium hydro-selenide. The mol-ecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C-NMe-C=C-C=C-C=C-NH). The C=Se bond length [1.838 (2) Å] corresponds well to those found in the close analogs and indicates its pronounced doub...

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1-Methyl-2-methyl­sulfanyl-6-nitro-1H-benzimidazole

The mol-ecule of the title compound, C9H9N3O2S, is built up from fused five- and six-membered rings connected to methyl-sulfanyl and nitro groups, respectively. The mean plane through the fused ring system is inclined slightly relative to the plane passing through the nitro group [dihedral angle = 3.6 (2)°]. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds and π-π inter-actions bet...

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6-Meth­oxy-2-methyl-1-m-tolyl-1H-benzimidazole hemihydrate

The title compound, C(16)H(16)N(2)O·0.5H(2)O, is a substituted 1-phenyl-benzimidazole, which belongs to the class of ATP-site inhibitors of the platelet-derived growth-factor receptor. In the crystal, the components are linked by an O-H⋯N hydrogen bond.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813020588